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If you want to get values of all columns of selected row from DBGrid component, then use Fields and FieldCount properties, like in this example.

procedure TForm1.Button1Click(Sender: TObject);
var
  i: Integer;
begin
  Memo1.Clear;
  with DBGrid1 do
  begin
    for i:=0 to FieldCount-1 do
      Memo1.Lines.Add(Fields[i].AsString);
  end;
end;